
Highlights
WHAT IS IT?
Eye serum with 6% retinoid complex
FEATURES
Wrinkle-fighting, collagen-supporting, soothing, smoothing, hydrating
BEST FOR
sensitive
CHECKS
Sulfate-free, Paraben-free, Gluten-free, Soy-free, Phthalate-free, Fragrance-free
Who Is It For?
Adults Concerned With Eye Area AgingWhat Does It Help With?
Wrinkles Fine Lines Hydration Eye Area RejuvenationBudget
Mid-range ($30-$75)How To Use
Which routine should it be used in?
Instructions:
Key Information
What Sunday Riley Says
Product Description:
A targeted and gentle anti-aging treatment for the delicate eye area, 5 Stars is a wrinkle-fighting serum powered by a 6% retinoid complex and bioactive centella asiatica to support skin's natural collagen. 5 Stars is also balanced with poppy seed extract and ceramides to soothe, smooth, and nurture the eye area while olive oil and shea butter rehydrate for overnight restoration.
About the Brand:
Ingredients Overview
Ingredients List
WATER/EAU/AQUA, DIMETHICONE, CAPRYLYL METHICONE, POLYGLYCERIN-6, DIMETHYL ISOSORBIDE, NIACINAMIDE, CETYL DIGLYCERYL TRIS(TRIMETHYLSILOXY)SILYLETHYL DIMETHICONE, HYDROGENATED POLYISOBUTENE, OCTYLDODECANOL, CAPRYLIC/CAPRIC TRIGLYCERIDE, PEG-12 DIMETHICONE/PPG-20 CROSSPOLYMER, OLEA EUROPAEA (OLIVE) FRUIT OIL, HYDROXYPINACOLONE RETINOATE, RETINOL, ASIATICOSIDE, MADECASSIC ACID, ASIATIC ACID, PAPAVER RHOEAS (RED POPPY) EXTRACT, BELLIS PERENNIS (DAISY) FLOWER EXTRACT, HIERACIUM PILOSELLA (HAWKWEED DAISY) EXTRACT, DIMETHICONE/VINYL DIMETHICONE CROSSPOLYMER, CERAMIDE NP, PENTYLENE GLYCOL, LECITHIN, METHYLPROPANEDIOL, POLYSORBATE 20, POTASSIUM PHOSPHATE, TOCOPHEROL, CAPRYLYL GLYCOL, POLYQUATERNIUM-80, DIDECYLDIMONIUM CHLORIDE, PENTAERYTHRITYL TETRA-DI-T-BUTYL HYDROXYHYDROCINNAMATE, BENZOTRIAZOLYL DODECYL P-CRESOL, ALCOHOL, SODIUM PHYTATE, CITRIC ACID, SODIUM CITRATE, SODIUM BENZOATE, SODIUM DEHYDROACETATE.
Key Ingredients
retinoid complex, centella asiatica, poppy seed extract, ceramides, olive oil, shea butter
Ingredients Details
Caprylic/capric Triglyceride
Common Name(s): Mct oil,fractionated coconut oil,c8/c10 triglyceride
CAS Number: 73398-61-5
DESCRIPTION
What It Does: Lightweight, stable emollient that solubilizes oil-soluble actives for excellent delivery without greasy feel.
Why It's Used: Universal lightweight emollient base and solubilizer for oil-soluble actives in serums and low-viscosity formulations where mineral oil or petrolatum would be too heavy.
How It Works: Medium-chain length provides ideal balance of spreading coefficient, penetration rate, and barrier-sealing properties. excellent solubilizer for vitamin e, retinoids, and other lipophilic actives.
Typically Found In: Serums,facial oils,sunscreens,anti-aging products,hair products
TECHNICAL DETAILS
Primary Category: Active ingredient โ medium-chain triglyceride emollient
Secondary Functions: Active solubilizer,spreading agent
Application Areas:
Facial Skincare
Body Care
Hair Care
Beard Care
Color Cosmetics (Makeup)
Dietary/Oral Supplements
Typical Concentration Range: 1%โ50%
SOURCING & ETHICS
Vegan Status: Yes โ from coconut/palm kernel oil
Halal Status: Yes
Source Notes: Fractionated by hydrolysis and re-esterification of coconut oil. only c8 and c10 fatty acids retained.
SKIN COMPATIBILITY
Irritancy Rating: 1/5 โ very low
Comedogenicity Rating: 1/5 โ very low; medium-chain length generally non-comedogenic
Sensitivity Concerns: Non-irritating.
Safe for Sensitive Skin: Yes
SAFETY & COMPATIBILITY
Safety Profile: Excellent safety profile. ewg score: 1.
Works Well With: Humectants,ceramides,actives as carrier
Avoid Combining With: No significant incompatibilities
SCIENTIFIC NOTE
Mct oil's medium-chain length (c8/c10) provides superior oxidative stability vs longer polyunsaturated chains and better skin aesthetics (lighter, less greasy) vs longer chain emollients (c16/c18). excellent solubilizer for retinoic acid, tocopheryl esters, and other lipophilic actives.
Last Verified: Cosing database,cir safety assessment,ewg skin deep
Primary Sources: 2026-03-12
Caprylyl Methicone
Common Name(s): Caprylyl methicone,specialty silicone polymer,conditioning performance silicone
CAS Number: N/a
DESCRIPTION
What It Does: Provides specialty silicone performance โ elastomeric skin feel, water-soluble silicone activity, or enhanced hair cuticle conditioning โ depending on the specific functional modification.
Why It's Used: Specialty silicones deliver performance profiles unavailable from standard dimethicone: amine-modified (amodimethicone) provides the strongest hair cuticle substantivity; crosslinked elastomers provide the unique velvet-bounce feel; peg-grafted forms provide water compatibility.
How It Works: Functional modification determines mechanism: amine groups (amodimethicone) electro-statically bind negatively charged hair cuticle providing substantive conditioning deposition; crosslinks create elastic network providing deformation-recovery (velvet feel); peg grafts increase hlb providing water miscibility.
Typically Found In: Hair conditioners,primers,specialty formulas
TECHNICAL DETAILS
Primary Category: Functional ingredient โ emollient
Secondary Functions: Barrier sealing,softening
Application Areas:
Facial Skincare
Body Care
Hair Care
Beard Care
Color Cosmetics (Makeup)
Dietary/Oral Supplements
Typical Concentration Range: 0.5%โ20%
SOURCING & ETHICS
Vegan Status: Yes
Halal Status: Yes
Source Notes: Plant-derived, synthetic or animal-derived. verify source.
SKIN COMPATIBILITY
Irritancy Rating: 1/5 โ very low
Comedogenicity Rating: 1/5 โ low; formulation-dependent
Sensitivity Concerns: Non-irritating.
Safe for Sensitive Skin: Yes
SAFETY & COMPATIBILITY
Safety Profile: Excellent safety profile. ewg score: 1.
Works Well With: Humectants,ceramides,actives as carrier
Avoid Combining With: No significant incompatibilities
SCIENTIFIC NOTE
Amodimethicone's amine groups have pka ~9 โ at typical conditioner ph 4โ5, they are fully protonated (โnhโโบ) providing maximum cationic character for electrostatic attraction to negatively charged damaged hair cuticle.
Last Verified: Cosing database,specialty silicone performance review
Primary Sources: 2026-03-12
Cetyl Diglyceryl Tris(trimethylsiloxy)silylethyl Dimethicone
Common Name(s): Cetyl diglyceryl tris(trimethylsiloxy)silylethyl dimethicone
DESCRIPTION
What It Does: Smooths and softens skin by filling intercorneocyte spaces, reducing friction, and providing a pleasant aesthetic skin feel in formulations.
Why It's Used: Synthetic esters provide tailored aesthetic properties โ spreadability, skin feel, volatility, refractive index โ that natural oils alone cannot consistently deliver.
How It Works: The ester molecule fills microscopic surface irregularities between corneocytes, reducing coefficient of friction, reflecting light uniformly, and providing a lubrication layer that protects the skin surface.
Typically Found In: Moisturizers,sunscreens,color cosmetics,body lotions,lip products
TECHNICAL DETAILS
Primary Category: Synthetic emollients
Secondary Functions: Emollient
Application Areas:
Facial Skincare
Body Care
Hair Care
Beard Care
Color Cosmetics (Makeup)
Dietary/Oral Supplements
Typical Concentration Range: 1โ20%
SOURCING & ETHICS
Vegan Status: Yes
Halal Status: Yes
Source Notes: Synthetically produced ester emollient; no animal components.
SKIN COMPATIBILITY
Irritancy Rating: 1
Comedogenicity Rating: 1
Sensitivity Concerns: Low sensitization potential at recommended use concentrations.
Safe for Sensitive Skin: Yes
SAFETY & COMPATIBILITY
Safety Profile: Well-characterized cosmetic ingredient with established safety profile. generally non-irritating at typical use concentrations. suitable for leave-on and rinse-off cosmetics.
Works Well With: Silicones,uv filters,other emollients
Avoid Combining With: Strongly alkaline conditions (risk of saponification of ester-type emollients)
SCIENTIFIC NOTE
The spreading coefficient of an emollient is governed by its surface tension, viscosity, and polarity. esters with branched alkyl chains (e.g., isopropyl, isostearyl) spread rapidly and leave a non-tacky film; linear long-chain esters provide more substantive moisturization. hlb value determines the preferred formulation system (w/o vs o/w emulsions).
Last Verified: Cosing eu database; pcpc cosmetic ingredient safety reviews; ingredient-specific safety and efficacy literature
Primary Sources: 2025-01-15
Dimethicone
Common Name(s): Pdms,polydimethylsiloxane,silicone fluid
CAS Number: 9006-65-9
DESCRIPTION
What It Does: Provides silicone-characteristic silky feel and skin protection with adjustable viscosity.
Why It's Used: The benchmark cosmetic silicone โ sets the gold standard for silky application feel, spreadability, and skin protection in virtually all skin care categories.
How It Works: Polydimethylsiloxane chain flexibility provides extremely low surface tension and high spreadability. inert si-o backbone provides chemical stability and excellent skin tolerance. occlusive film formation reduces tewl. higher viscosity grades provide more intense conditioning.
Typically Found In: Moisturizers,foundations,primers,sunscreens โ nearly universal
TECHNICAL DETAILS
Primary Category: Functional ingredient โ polydimethylsiloxane
Secondary Functions: Barrier sealing,softening
Application Areas:
Facial Skincare
Body Care
Hair Care
Beard Care
Color Cosmetics (Makeup)
Dietary/Oral Supplements
Typical Concentration Range: 0.1%โ30%
SOURCING & ETHICS
Vegan Status: Yes โ synthetic
Halal Status: Yes
Source Notes: Plant-derived, synthetic or animal-derived. verify source.
SKIN COMPATIBILITY
Irritancy Rating: 1/5 โ very low
Comedogenicity Rating: 1/5 โ low; formulation-dependent
Sensitivity Concerns: Non-irritating.
Safe for Sensitive Skin: Yes
SAFETY & COMPATIBILITY
Safety Profile: Excellent safety profile. ewg score: 1.
Works Well With: Humectants,ceramides,actives as carrier
Avoid Combining With: No significant incompatibilities
SCIENTIFIC NOTE
Dimethicone's exceptional silky feel arises from its very low intermolecular attractive forces (weak van der waals forces due to non-polar methyl groups) that allow silicone chains to slide freely over skin. the coefficient of kinetic friction for pdms against skin (~0.04) is among the lowest of any cosmetic material โ explaining why even small amounts transform product feel.
Last Verified: Cosing database,cir safety assessment
Primary Sources: 2026-03-12